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采用硝酸盐-柠檬酸燃烧法合成了单一电解质 Ce0. 8Gd0. 1Tm0. 1O2-α，再将 Ce0. 8Gd0. 1Tm0. 1O2-α粉和二元硫酸盐( K_2SO4、Li_2SO4) 混合，重量比为 7 ∶ 3，制备得到 Ce0. 8Gd0. 1Tm0. 1O2-α-KLi SO4复合电解质。用 X 射线衍射( XRD) 测定了 Ce0. 8Gd0. 1Tm0. 1O2-α和 Ce0. 8Gd0. 1Tm0. 1O2-α- KLi SO4的晶体结构。用电化学工作站测量Ce0. 8Gd0. 1Tm0. 1O2-α-KLi SO4在 500～800 ℃和不同氧分压范围内的交流阻抗谱。结果表明: 在相同的测试温度条件下，Tm3+和 Gd3+双掺杂 Ce O2电解质电导率高于单掺杂 Ce O2电解质，是单一电解质的 2 倍。
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基本信息:
DOI：10.19703/j.bbgu.2096-7276.2021.04.0026
中图分类号:TQ133.3;TM911.4
引用信息:
[1]陈卫,胡文丽.Tm~(3+)和Gd~(3+)双掺杂CeO_2复合电解质的合成及其中温电性能[J].北部湾大学学报,2021,36(04):26-30.DOI:10.19703/j.bbgu.2096-7276.2021.04.0026.
基金信息:
安徽省高校自然科学研究重点项目(KJ2020A1148,KJ2019A1273); 安徽省教育厅教研重点项目(2020jyxm1426)